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1.
Compr Rev Food Sci Food Saf ; 23(3): e13343, 2024 May.
Artigo em Inglês | MEDLINE | ID: mdl-38629458

RESUMO

Innovations in food packaging systems could meet the evolving needs of the market; emerging concepts of non-migrating technologies reduce the negative migration of preservatives from packaging materials, extend shelf life, and improve food quality and safety. Non-migratory packaging activates the surface of inert materials through pretreatment to generate different active groups. The preservative is covalently grafted with the resin of the pretreated packaging substrate through the graft polymerization of the monomer and the coupling reaction of the polymer chain. The covalent link not only provides the required surface properties of the material for a long time but also retains the inherent properties of the polymer. This technique is applied to the processing for durable, stable, and easily controllable packaging widely. This article reviews the principles of various techniques for packaging materials, surface graft modification, and performance characterization of materials after grafting modification. Potential applications in the food industry and future research trends are also discussed.


Assuntos
Embalagem de Alimentos , Armazenamento de Alimentos , Embalagem de Alimentos/métodos , Polímeros/química , Qualidade dos Alimentos
2.
J Agric Food Chem ; 72(15): 8805-8816, 2024 Apr 17.
Artigo em Inglês | MEDLINE | ID: mdl-38566515

RESUMO

Traditional petroleum-based food-packaging materials have poor permeability, limited active packaging properties, and difficulty in biodegradation, limiting their application. We developed a carboxymethylated tamarind seed polysaccharide composite film incorporated with ε-polylysine (CTPε) for better application in fresh-cut agricultural products. The CTPε films exhibit excellent water vapor barrier properties, but the mechanical properties are slightly reduced. Fourier transform infrared spectroscopy and X-ray diffraction spectra indicate the formation of hydrogen bonds between ε-PL and CTP, leading to their internal reorganization and dense network structure. With the increase of ε-PL concentration, composite films showed notable inhibition of postharvest pathogenic fungi and bacteria, a significant enhancement of 2,2'- azino-bis (3-ethylbenzothiazoline-6-sulfonic acid) radical-scavenging activity, and gradual improvement of wettability performance. Cytotoxicity experiments confirmed the favorable biocompatibility when ε-PL was added at 0.3% (CTPε2). In fresh-cut bell pepper preservation experiments, the CTPε2 coating effectively delayed weight loss and malondialdehyde increase preserved the hardness, color, and nutrients of fresh-cut peppers and prolonged the shelf life of the fresh-cut peppers, as compared with the control group. Therefore, CTPε composite films are expected to be a valuable packaging material for extending the shelf life of freshly cut agricultural products.


Assuntos
Capsicum , Quitosana , Tamarindus , Antioxidantes/farmacologia , Antioxidantes/análise , Polilisina/farmacologia , Polilisina/química , Capsicum/microbiologia , Antibacterianos/farmacologia , Antibacterianos/química , Embalagem de Alimentos , Polissacarídeos/farmacologia , Sementes/química , Quitosana/química
3.
Compr Rev Food Sci Food Saf ; 23(3): e13333, 2024 May.
Artigo em Inglês | MEDLINE | ID: mdl-38571439

RESUMO

Recently, food spoilage caused by pathogens has been increasing. Therefore, applying control strategies is essential. Bacteriophages can potentially reduce this problem due to their host specificity, ability to inhibit bacterial growth, and extend the shelf life of food. When bacteriophages are applied directly to food, their antibacterial activity is lost. In this regard, bacteriophage-loaded biopolymers offer an excellent option to improve food safety by extending their shelf life. Applying bacteriophages in food preservation requires comprehensive and structured information on their isolation, culturing, storage, and encapsulation in biopolymers for active food packaging applications. This review focuses on using bacteriophages in food packaging and preservation. It discusses the methods for phage application on food, their use for polymer formulation and functionalization, and their effect in enhancing food matrix properties to obtain maximum antibacterial activity in food model systems.


Assuntos
Bacteriófagos , Embalagem de Alimentos , Embalagem de Alimentos/métodos , Alimento Funcional , Biopolímeros , Antibacterianos
4.
Compr Rev Food Sci Food Saf ; 23(3): e13339, 2024 May.
Artigo em Inglês | MEDLINE | ID: mdl-38578165

RESUMO

The importance of food quality and safety lies in ensuring the best product quality to meet consumer demands and public health. Advanced technologies play a crucial role in minimizing the risk of foodborne illnesses, contamination, drug residue, and other potential hazards in food. Significant materials and technological advancements have been made throughout the food supply chain. Among them, quantum dots (QDs), as a class of advanced nanomaterials with unique physicochemical properties, are progressively demonstrating their value in the field of food quality and safety. This review aims to explore cutting-edge research on the different applications of QDs in food quality and safety, including encapsulation of bioactive compounds, detection of food analytes, food preservation and packaging, and intelligent food freshness indicators. Moreover, the modification strategies and potential toxicities of diverse QDs are outlined, which can affect performance and hinder applications in the food industry. The findings suggested that QDs are mainly used in analyte detection and active/intelligent food packaging. Various food analytes can be detected using QD-based sensors, including heavy metal ions, pesticides, antibiotics, microorganisms, additives, and functional components. Moreover, QD incorporation aided in improving the antibacterial and antioxidant activities of film/coatings, resulting in extended shelf life for packaged food. Finally, the perspectives and critical challenges for the productivity, toxicity, and practical application of QDs are also summarized. By consolidating these essential aspects into this review, the way for developing high-performance QD-based nanomaterials is presented for researchers and food technologists to better capitalize upon this technology in food applications.


Assuntos
Pontos Quânticos , Pontos Quânticos/toxicidade , Contaminação de Alimentos/prevenção & controle , Contaminação de Alimentos/análise , Microbiologia de Alimentos , Qualidade dos Alimentos , Embalagem de Alimentos/métodos
5.
Waste Manag ; 178: 362-370, 2024 Apr 15.
Artigo em Inglês | MEDLINE | ID: mdl-38430750

RESUMO

Despite international efforts to foster the circular economy, plastic waste remains a major environmental problem. In the circular economy, the success of a waste management system depends, inter alia, on consumers properly sorting their plastic waste. Yet mis-sorting of plastic food packaging waste happens routinely. We sought to find out why and to outline the ways consumers prefer to receive information about waste sorting procedures. Tailoring information to consumer preferences can improve the effectiveness of waste management policy. Using the Motivation Opportunity Ability (MOA) framework to explain consumer behaviour, we conducted focus group discussions in two German cities. Our findings suggest that more accurate information and financial incentives best motivate consumers to sort waste correctly. Uncertainty and confusion over the packaging material are the most severe hindrances to correct sorting behaviour. The Internet and social media are preferred most for acquiring information on how to sort plastic food packaging correctly. Policymakers can use our results to adjust packaging and waste management regulations to help eliminate confusion among consumers and to facilitate their recycling intentions. Food industry practitioners and company decision makers can use our results to adjust their plastic packaging features to better match consumer preferences for easily recyclable waste.


Assuntos
Plásticos , Gerenciamento de Resíduos , Humanos , Embalagem de Alimentos , 60659 , Grupos Focais , Reciclagem , Embalagem de Produtos , Alemanha
6.
Molecules ; 29(6)2024 Mar 21.
Artigo em Inglês | MEDLINE | ID: mdl-38543030

RESUMO

Improving the shelf lives of fruits is challenging. The biodegradable polysaccharide pullulan exhibits excellent film-forming ability, gas barrier performance, and natural decomposability, making it an optimal material for fruit preservation. To overcome problems of high cost and film porosity of existing packaging technologies, we aimed to develop pullulan-based packaging paper to enhance the shelf lives of fruits. A thin paper coating comprising a mixture of 15 wt.% pullulan solution at various standard viscosities (75.6, 77.8, and 108.5 mPa·s) with tea polyphenols (15:2) and/or vitamin C (150:1) improved the oxygen transmission rate (120-160 cm3 m-2·24 h·0.1 MPa), water vapor transmission rate (<5.44 g·mm-1 m-2·h·kPa), maximum free radical clearance rate (>87%), and antibacterial properties of base packaging paper. Grapes wrapped with these pullulan-based papers exhibited less weight loss (>4.41%) and improved hardness (>16.4%) after 10 days of storage compared to those of control grapes (wrapped in untreated/base paper). Grapes wrapped with pullulan-based paper had >12.6 wt.% total soluble solids, >1.5 mg/g soluble protein, >0.44 wt.% titratable acidity, and ≥4.5 mg 100 g-1 ascorbic acid. Thus, pullulan-based paper may prolong the shelf life of grapes with operational convenience, offering immense value for fruit preservation.


Assuntos
Conservação de Alimentos , Frutas , Glucanos , Frutas/microbiologia , Preservação Biológica , Ácido Ascórbico/farmacologia , Embalagem de Alimentos
7.
Int J Biol Macromol ; 265(Pt 2): 130987, 2024 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-38508559

RESUMO

Among the common natural biomolecules, the excellent properties of proteins have attracted extensive attention from researchers for functional applications, however, in native form proteins have many limitations in the performance of their functional attribute. However, with the deepening of research, it has been found that the combination of natural active substances such as polyphenols, polysaccharides, etc. with protein molecules will make the composite system have stronger functional properties, while the utilization of pH-driven method, ultrasonic treatment, heat treatment, etc. not only provides a guarantee for the overall protein-based composite system, but also gives more possibilities to the protein-composite system. Protein composite systems are emerging in the fields of novel active packaging, functional factor delivery systems and gel systems with high medical value. The products of these protein composite systems usually have high functional properties, mainly due to the interaction of the remaining natural active substances with protein molecules, which can be broadly categorized into covalent interactions and non-covalent interactions, and which, despite the differences in these interactions, together constitute the cornerstone for the stability of protein composite systems and for in-depth research.


Assuntos
Alimentos , Hipertermia Induzida , Embalagem de Medicamentos , Polifenóis , Embalagem de Produtos , Embalagem de Alimentos
8.
Int J Biol Macromol ; 265(Pt 2): 130520, 2024 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-38553390

RESUMO

Starch-derived films exhibit significant potential for packaging applications owing to their low cost, biodegradable characteristics, and natural abundance. Nonetheless, there is a demand to enhance their mechanical properties and moisture resistance to broaden their use. In this study, high performing sorbitol-plasticized starch/Ti3C2Tx MXene nanocomposites, reinforced with ultra-low filler contents, were fabricated for the first time in literature. The MXene nanoplatelets were well-dispersed within the starch matrix while there was a tendency for the fillers to align in-plane, as revealed by polarized Raman spectroscopy. The produced nanocomposite films demonstrate remarkable effectiveness in blocking UV light, offering an additional valuable attribute in food packaging. The Young's modulus and tensile strength of starch films containing 0.75 wt% MXene increased from 439.9 and 11.0 MPa to 764.3 and 20.8 MPa, respectively. The introduction of 1 wt% MXene nanoplatelets reduced the water vapour permeability of starch films from 2.78 × 10-7 to 1.80 × 10-7 g/m h Pa due to the creation of highly tortuous paths for water molecules. Micromechanical theories were also implemented to understand further the reinforcing mechanisms in the biobased nanocomposites. The produced starch nanocomposites not only capitalize on the biodegradable and renewable nature of starch but also harness the unique properties of nanomaterials, paving the way for sustainable and high-performance packaging solutions that align with both consumer and environmental demands.


Assuntos
Nanocompostos , Nitritos , Amido , Elementos de Transição , Amido/química , Titânio/química , Nanocompostos/química , Resistência à Tração , Embalagem de Alimentos/métodos
9.
Int J Biol Macromol ; 265(Pt 1): 130466, 2024 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-38432274

RESUMO

A novel colorimetric aerogel was developed by the complexation of carboxymethyl cellulose (CMC), sodium alginate (SA), and black goji anthocyanin (BGA) followed by freeze-drying for monitoring fish (Coho salmon) freshness during storage at 4 °C and 25 °C. The various aerogels (C/S/B3:1, C/S/B2:1, C/S/B1:1, C/S/B1:2, and C/S/B1:3) externally and internally were characterized using SEM, FTIR, XRD, DSC, and TGA. Among them, the aerogel composite C/S/B1:2 exhibited the most uniform pore size, largest specific surface area, rapid color changes in various alkaline vapors (5 µM and 50 µM), and better mechanical strength. Furthermore, the colorimetric aerogel became dark blue from light purple during fish storage at temperatures of 4 °C and 25 °C when it reached pH 7.49 and 7.33, TVC 8.9 × 107 CFU/g and 8.5 × 107 CFU/g, and TVB-N 33.8 mg/100 g and 26.12 mg/100 g, respectively, indicating fish completely deteriorated. Taken together, the colorimetric aerogel composite C/S/B1:2 was promising for determining fish freshness, which could be utilized as a non-destructive and useful intelligent sensor in monitoring various fish and meat freshness and/or quality.


Assuntos
Alginatos , Carboximetilcelulose Sódica , Animais , Carboximetilcelulose Sódica/química , Antocianinas/química , Colorimetria , Embalagem de Alimentos
10.
Int J Biol Macromol ; 265(Pt 1): 130651, 2024 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-38462113

RESUMO

The continuous development of sustainable food-active packaging materials and practices with high performance is a response to the increasing challenges posed by microbial food safety and environmental contamination. In this study, a multifunctional bio-nanocomposite composed primarily of chitosan, cellulose nanomaterials and carvacrol was proposed as a conformal coating for fruit preservation. The coating exhibits excellent antioxidant and antibacterial activities owing to the incorporation of the carvacrol. The inhibition rate of the coating on E. coli and S. aureus is enhanced by 57.13 % and 62.18 %, respectively. And its antioxidant activities is also improved by 77.45 %. In addition, the oxygen permeability (OP) and water vapor permeability (WVP) of this CS/CNC coating are significantly lowered by 67 % and 46 %, respectively, comparing with the CS coating. The coating exhibited excellent biosafety and cytocompatibility because of over 90 % of the HepG2 cells remained alive in each concentration of the coating after 24 h incubation. Additionally, the efficacy of the coating in prolonging the freshness and visual appeal of perishable fruits is substantiated by the experiment involving two fruit specimens. Furthermore, the coating's ease of production, ingestibility, washability, and utilization of cost-effective and easily accessible biomaterials, including renewable waste materials, indicate its potential as a viable economic substitute for commercially accessible fruit coatings.


Assuntos
Quitosana , Cimenos , Nanocompostos , Nanopartículas , Quitosana/química , Frutas/química , Escherichia coli , Celulose/química , Staphylococcus aureus , Antioxidantes/farmacologia , Antioxidantes/análise , Embalagem de Alimentos , Nanopartículas/química , Antibacterianos/farmacologia , Nanocompostos/química
11.
Int J Biol Macromol ; 265(Pt 1): 130714, 2024 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-38462116

RESUMO

In this study, hydrophobic sodium alginate/anthocyanin/cellulose nanocrystal indicator films were fabricated by incorporating nanosilica (NS) as a waterproofing layer. The concentrations and formation methods (spraying (S), coating (C), and impregnation (I)) of the NS layer (denoted as NSS, NSC, NSI, respectively) were optimized. The results indicated that the optimum concentration of the NS layer was 5 % at a water contact angle (WCA) 110.5°. Further, Fourier transform infrared spectra showed the presence of SiOSi and SiCH3 groups in the NSS, NSC, and NSI films, and X-ray diffraction spectra indicated that original structures of these films were disordered. Moreover, the surface morphology, mechanical properties, and light transmission were affected by the NS layer, and the optimal layer was found to be NSI. After 10 days of storage at 100 % humidity, the NSI film exhibited low water vapor adsorption (37.22 g) and permeability (0.1484 g/m·s·Pa·10-11) and a high WCA (110.2°). In addition, the NSI film exhibited a visible color shift with an increasing pH of the buffer solution. A monitoring test of fish freshness showed that the NSI film displayed a distinctive color change corresponding to fish spoilage during 14 days of storage. This indicates that NSI has high potential in indicator film applications.


Assuntos
Alginatos , Antocianinas , Animais , Adsorção , Celulose , Peixes , Sódio , Embalagem de Alimentos , Concentração de Íons de Hidrogênio
12.
Int J Biol Macromol ; 265(Pt 1): 130765, 2024 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-38462119

RESUMO

Essential oils (EOs) are liquid extracts derived from various parts of herbal or medicinal plants. They are widely accepted in food packaging due to their bioactive components, which exhibit remarkable antioxidant and antimicrobial properties against various pathogenic and food spoilage microorganisms. However, the functional efficacy of EOs is hindered by the high volatility of their bioactive compounds, leading to rapid release. Combining biopolymers with EOs forms a complex network within the polymeric matrix, reducing the volatility of EOs, controlling their release, and enhancing thermal and mechanical stability, favoring their application in food packaging or processing industries. This study presents a comprehensive overview of techniques used to encapsulate EOs, the natural polymers employed to load EOs, and the functional properties of EOs-loaded biopolymeric particles, along with their potential antioxidant and antimicrobial benefits. Additionally, a thorough discussion is provided on the widespread application of EOs-loaded biopolymers in the food industries. However, research on their utilization in confectionery processing, such as biscuits, chocolates, and others, remains limited. Further studies can be conducted to explore and expand the applications of EOs-loaded biopolymeric particles in food processing industries.


Assuntos
Anti-Infecciosos , Óleos Voláteis , Óleos Voláteis/farmacologia , Antioxidantes/farmacologia , Indústria de Processamento de Alimentos , Embalagem de Alimentos/métodos , Biopolímeros , Polímeros , Indústria Alimentícia
13.
Int J Biol Macromol ; 265(Pt 1): 130813, 2024 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-38479667

RESUMO

In this study, an active and intelligent nanofilm for monitoring and maintaining the freshness of pork was developed using ethyl cellulose/gelatin matrix through electrospinning, with the addition of natural purple sweet potato anthocyanin. The nanofilm exhibited discernible color variations in response to pH changes, and it demonstrated a higher sensitivity towards volatile ammonia compared with casting film. Notably, the experimental findings regarding the wettability and pH response performance indicated that the water contact angle between 70° and 85° was more favorable for the smart response of pH sensitivity. Furthermore, the film exhibited desirable antioxidant activities, water vapor barrier properties and also good antimicrobial activities with the incorporation of ε-polylysine, suggesting the potential as a food packaging film. Furthermore, the application preservation outcomes revealed that the pork packed with the nanofilm can prolong shelf life to 6 days, more importantly, a distinct color change aligned closely with the points indicating the deterioration of the pork was observed, changing from light pink (indicating freshness) to light brown (indicating secondary freshness) and then to brownish green (indicating spoilage). Hence, the application of this multifunctional film in intelligent packaging holds great potential for both real-time indication and efficient preservation of the freshness of animal-derived food items.


Assuntos
Celulose/análogos & derivados , Carne de Porco , Carne Vermelha , Suínos , Animais , Gelatina , Ração Animal , Antocianinas , Embalagem de Alimentos , Concentração de Íons de Hidrogênio
14.
Int J Biol Macromol ; 265(Pt 1): 130798, 2024 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-38479674

RESUMO

Controlling ethylene production and microbial infection are key factors to prolong the shelf life of climacteric fruit. Herein, a nanocomposite film, hexanal-loaded ZIF-8/CS (HZCF) with "nano-barrier" structure, was developed by a one-pot co-crystallized of ZIF-8 in situ growth on quaternized chitosan (CS) and encapsulation of hexanal into ZIF-8 via microporous adsorption. The resultant film realized the temperature responsive release of hexanal via the steric hindrance and hierarchical pore structure as "nano-barrier", which can inhibit ethylene production in climacteric fruit on demand. Based on this, the maximum ethylene inhibition rate of HZCF was up to 52.6 %. Meanwhile, the film exhibits excellent antibacterial, mechanical, UV resistance and water retention properties, by virtue of the functional synergy between ZIF-8 and CS. Contributed to the multifunctional features, HZCF prolonged the shelf life of banana and mango for at least 16 days, which is 8 days longer than that of control fruit. More strikingly, HZCF is washable and biodegradable, which is expected to replace non-degradable plastic film. Thus, this study provides a convenient novel approach to simplify the encapsulation of active molecule on metal-organic frameworks (MOFs), develops a packaging material for high-efficient freshness preservation, and helps to alleviate the survival crisis caused by food waste.


Assuntos
Aldeídos , Quitosana , Climatério , Eliminação de Resíduos , Quitosana/farmacologia , Quitosana/química , Frutas , Temperatura , Etilenos/química , Antibacterianos/farmacologia , Embalagem de Alimentos
15.
Int J Biol Macromol ; 265(Pt 1): 130899, 2024 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-38490375

RESUMO

The development of biodegradable active packaging films with hydrophobic characteristics is vital for extending the shelf life of food and reducing the reliance on petroleum-based plastics. In this study, novel hydrophobic cerium-based metal-organic framework (Ce-MOF) nanoparticles were successfully synthesized. The Ce-MOF nanoparticles were then incorporated into the cassava starch matrix at varying concentrations (0.5 %, 1.5 %, 3 %, and 4 % w/w of total solid) to fabricate cassava-based active packaging films via the solution casting technique. The influence of Ce-MOF on the morphology, thermal attributes, and physicochemical properties of the cassava film was subsequently determined through further analyses. Biomedical analysis including antioxidant activity and the cellular morphology evaluation in the presence of the films was also conducted. The results demonstrated that the consistent dispersion of Ce-MOF nanofillers within the cassava matrix led to a significant enhancement in the film's crystallinity, thermal stability, antioxidant activity, biocompatibility, and hydrophobicity. The introduction of Ce-MOF also contributed to the film's reduced water solubility. Considering these outcomes, the developed cassava/Ce-MOF films undoubtedly have significant potential for active food packaging applications.


Assuntos
Embalagem de Alimentos , Estruturas Metalorgânicas , Embalagem de Alimentos/métodos , Antioxidantes , Permeabilidade , Amido/química
16.
Sci Rep ; 14(1): 7356, 2024 03 28.
Artigo em Inglês | MEDLINE | ID: mdl-38548906

RESUMO

Packaging is very important to maintain the quality of food and prevent the growth of microbes. Therefore, the use of food packaging with antimicrobial properties protects the food from the growth of microorganisms. In this study, antibacterial nanocomposite films of polyvinyl alcohol/starch/chitosan (PVA/ST/CS) together with nickel oxide-copper oxide nanoparticles (NiO-CuONPs) are prepared for food packaging. NiO-CuONPs were synthesized by the co-precipitation method, and structural characterization of nanoparticles (NPs) was carried out by XRD, FTIR, and SEM techniques. Composites of PVA/ST/CS, containing different percentages of NPs, were prepared by casting and characterized by FTIR and FESEM. The mechanical properties, diffusion barrier, and thermal stability were determined. The nanoparticles have a round structure with an average size of 6.7 ± 1.2 nm. The cross-section of PVA/ST/CS film is dense, uniform, and without cracks. In the mechanical tests, the addition of NPs up to 1% improved the mechanical properties (TS = 31.94 MPa), while 2% of NPs lowered TS to 14.76 MPa. The fibroblast cells toxicity and the films antibacterial activity were also examined. The films displayed stronger antibacterial effects against Gram-positive bacteria (Staphylococcus aureus) compared to Gram-negative bacteria (Escherichia coli). Furthermore, these films have no toxicity to fibroblast cells and the survival rate of these cells in contact with the films is more than 84%. Therefore, this film is recommended for food packaging due to its excellent mechanical and barrier properties, good antibacterial activity, and non-toxicity.


Assuntos
Quitosana , Nanopartículas , Quitosana/farmacologia , Quitosana/química , Embalagem de Alimentos/métodos , Álcool de Polivinil/química , Amido , Antibacterianos/farmacologia , Antibacterianos/química , Nanopartículas/química
17.
Biomolecules ; 14(3)2024 Mar 08.
Artigo em Inglês | MEDLINE | ID: mdl-38540743

RESUMO

Laccase from Trametes versicolor was applied to produce phenolic polymeric compounds with enhanced properties, using a wine lees extract as the phenolic source. The influence of the incubation time on the progress of the enzymatic oxidation and the yield of the formed polymers was examined. The polymerization process and the properties of the polymeric products were evaluated with a variety of techniques, such as high-pressure liquid chromatography (HPLC) and gel permeation chromatography (GPC), Fourier-transform infrared (FTIR) and nuclear magnetic resonance (NMR) spectroscopies, differential scanning calorimetry (DSC), and thermogravimetric analysis (TGA). The enzymatic polymerization reaction resulted in an 82% reduction in the free phenolic compounds of the extract. The polymeric product recovery (up to 25.7%) and the molecular weight of the polymer depended on the incubation time of the reaction. The produced phenolic polymers exhibited high antioxidant activity, depending on the enzymatic oxidation reaction time, with the phenolic polymer formed after one hour of enzymatic reaction exhibiting the highest antioxidant activity (133.75 and 164.77 µg TE mg-1 polymer) towards the ABTS and DPPH free radicals, respectively. The higher thermal stability of the polymeric products compared to the wine lees phenolic extract was confirmed with TGA and DSC analyses. Finally, the formed phenolic polymeric products were incorporated into chitosan films, providing them with increased antioxidant activity without affecting the films' cohesion.


Assuntos
Antioxidantes , Vinho , Antioxidantes/química , Lacase/química , Vinho/análise , Polímeros/química , Trametes , Embalagem de Alimentos , Fenóis/química , Extratos Vegetais/análise
18.
Environ Sci Technol ; 58(13): 5670-5684, 2024 Apr 02.
Artigo em Inglês | MEDLINE | ID: mdl-38501683

RESUMO

PFASs are linked to serious health and environmental concerns. Among their widespread applications, PFASs are known to be used in food packaging and directly contribute to human exposure. However, information about PFASs in food packaging is scattered. Therefore, we systematically map the evidence on PFASs detected in migrates and extracts of food contact materials and provide an overview of available hazard and biomonitoring data. Based on the FCCmigex database, 68 PFASs have been identified in various food contact materials, including paper, plastic, and coated metal, by targeted and untargeted analyses. 87% of these PFASs belong to the perfluorocarboxylic acids and fluorotelomer-based compounds. Trends in chain length demonstrate that long-chain perfluoroalkyl acids continue to be found, despite years of global efforts to reduce the use of these substances. We utilized ToxPi to illustrate that hazard data are available for only 57% of the PFASs that have been detected in food packaging. For those PFASs for which toxicity testing has been performed, many adverse outcomes have been reported. The data and knowledge gaps presented here support international proposals to restrict PFASs as a group, including their use in food contact materials, to protect human and environmental health.


Assuntos
Fluorocarbonos , Poluentes Químicos da Água , Humanos , Fluorocarbonos/análise , Embalagem de Alimentos , Alimentos , Poluentes Químicos da Água/análise
19.
Carbohydr Polym ; 334: 122043, 2024 Jun 15.
Artigo em Inglês | MEDLINE | ID: mdl-38553239

RESUMO

Here, we prepared ionically crosslinked films using pectin extracted from agro-wastes, specifically ambarella peels (AFP) and jackfruit seed slimy sheath (JFS). Physiochemical properties of pectins, including moisture content, molecular weight (Mw), degree of esterification (DE), and galacturonic acid (GA), were analyzed. Optimal extraction was determined, i.e., citric acid concentration 0.3 M, time 60 min, solid/liquid ratio 1:25, and temperature 90 °C for AFP or 85 °C for JFS. Pectin yields under these conditions were 29.67 % ± 0.35 % and 29.93 ± 0.49 %, respectively. AFP pectin revealed Mw, DE, and GA values of 533.20 kDa, 67.08 % ± 0.68 %, and 75.39 ± 0.82 %, while JFS pectin exhibited values of 859.94 kDa, 63.04 % ± 0.47 %, and 78.63 % ± 0.71 %, respectively. The pectin films crosslinked with Ca2+, Cu2+, Fe3+, or Zn2+ exhibited enhanced tensile strength and Young's modulus, along with reduced elongation at break, moisture content, water solubility, water vapor permeability, and oxygen permeability. Structural analyses indicated metal ions were effectively crosslinked with carboxyl groups of pectin. Notably, the Cu2+-crosslinked film demonstrated superior water resistance, mechanical properties, and exhibited the highest antioxidant and antibacterial activities among all tested films. Therefore, the pectin films represent a promising avenue to produce eco-friendly food packaging materials with excellent properties.


Assuntos
Artocarpus , Pectinas , Artocarpus/química , Embalagem de Alimentos , Frutas/química , Íons/análise , Pectinas/química , Sementes
20.
J Food Sci ; 89(4): 2423-2437, 2024 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-38433384

RESUMO

Excessive use of single-use plastic packaging presents an imminent threat to the environment. One of the emerging solutions is using edible food packaging. However, there is lack of consumer information toward edible packaging. This study evaluated consumer attitude, acceptability, and purchase intent of three types of edible food packaging: muffin liner, cranberry pomace fruit leather wrap, and powdered drink sachet. One hundred consumers who frequently consumed muffins, strawberry fruit leather, and powdered lemonade were selected from metropolitan area of Portland, Oregon to participate in the study. The panelists were presented with the edible films and the food products with the edible packaging, information card highlighting the environmental-friendly edible package, and were prompted with describing the sensory attributes, purchase intent, and qualities regarding the edible packaging with and without food. Overall, panelists liked the three foods with the edible packaging giving overall liking scores of 7.48, 8.06, and 7.48 for the muffin liners, edible fruit leather wraps, and powdered drink sachets, respectively, based on a 9-point hedonic scale where 1 = dislike extremely and 9 = like extremely. When asked about hypothetical purchase intent, 64%-68% of panelists positively reacted to purchase intent and would buy all three types of edible packaging products. Based on the positive reaction from panelists, edible packaging maybe a possible solution to reducing single-use plastic packaging in the food industry. This study can be the catalyst for further investigation of the efficacy of different applications of edible food packaging as well as consumer perceptions of eating their packaging. PRACTICAL APPLICATION: Edible food packaging is an emerging solution for reducing single-use plastic waste. This study investigated consumer attitude, acceptability, and purchase intent of edible food packaging for three food packaging applications, including edible muffin liner, fruit leather wrap, and powdered drink sachet. This study demonstrated that consumers strongly agree that edible packaging would serve as an environmentally sustainable solution to single-use plastics, and are willing to spend more to purchase these sustainable alternatives. This study provides new information toward the future development of edible packaging and consumer perceptions of eating their packaging.


Assuntos
Filmes Comestíveis , Paladar , Emoções , Embalagem de Alimentos , Percepção , Comportamento do Consumidor
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